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Molecular Theory of Solutions, by Arieh Ben-Naim
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This book presents new and updated developments in the molecular theory of mixtures and solutions. It is based on the theory of Kirkwood and Buff which was published more than fifty years ago. This theory has been dormant for almost two decades. It has recently become a very powerful and general tool to analyze, study and understand any type of mixtures from the molecular, or the microscopic point of view. The traditional approach to mixture has been, for many years, based on the study of excess thermodynamic quantities. This provides a kind of global information on the system. The new approach provides information on the local properties of the same system. Thus, the new approach supplements and enriches our information on mixtures and solutions.
- Sales Rank: #3013591 in Books
- Published on: 2006-10-05
- Original language: English
- Number of items: 1
- Dimensions: 6.70" h x .70" w x 9.60" l, 1.81 pounds
- Binding: Paperback
- 400 pages
Review
"I recommend the book for its clarity, content and fresh insight into the molecular theory of solutions."-- ACS
"The book will serve for decades as a major reference in the field."--Robert M. Mazo, University of Oregon
About the Author
ARIEH BEN-NAIM
Professor of Physical Chemistry
The Hebrew University
Givat Ram, Jerusalem, Israel
Temporary address for correspondence:
Departamento de Quimica
Universidad de Burgos, 09001
Burgos,Spain
arieh@fh.huji.ac.il
Born in Jerusalem, Israel. I did my Masters and PhD at The Hebrew University of Jerusalem. I did my post doctorate at the University of Stony Brook and at Bell Laboratories. I had been teaching at The Hebrew University of Jerusalem since 1967. During my numerous travels, I taught and collaborated in various universities and research institutes around the world.
Most helpful customer reviews
0 of 0 people found the following review helpful.
Excellent volume but only for the seasoned statistical mechanic
By Roberta Bleu
Excellent volume but only for the seasoned statistical mechanic. A good introduction to Kirkwood/Buff theory which is the main strength of this work. Novices in solution thermodynamics would be advised to steer clear.
5 of 5 people found the following review helpful.
New book on solutions
By Jay Rasaiah
This is an important book that provides a clear account of the molecular theory of solutions and mixtures based mainly on the Kirkwood-Buff theory that was developed many years ago. The theory could not have been fully exploited until Ben-Naim developed methods to calculate the Kirkwood-Buff (KB) integrals from experimental data rather than from the pair correlation functions.
The KB integrals, as well as some derived quantities, provide information about the local properties of the system, as opposed to their global properties described by the excess thermodynamic functions that were and are commonly used. Ben-Naim also introduced a new measure of the thermodynamics of solvation that does not depend on hypothetical standard states that were traditionally part of solution chemistry. The book is written very clearly and the arguments are carefully presented and illustrated with examples. It is strongly recommended for both the beginning graduate student and experienced scientist with interests in solutions.
4 of 4 people found the following review helpful.
Don't hesitate, buy it!
By Nico van der Vegt
This is an excellent book that highly succeeds in explaining a difficult subject! Thermodynamics of solution mixtures has a long history and much has been written on this topic. I am amongst those of you that have been confused from time to time by the various definitions of excess functions, activity coefficients and reference states. In "Molecular Theory of Solutions", Ben-Naim introduces the reader to the elementary statistical mechanics of liquids and solution mixtures. A central theme of the book is the Kirkwood-Buff (KB) theory of solution, which, as originally shown by Ben-Naim, can be used to extract (local) molecular properties from (global) thermodynamic properties. Ben-Naim next uses KB theory to derive a thermodynamic formalism for ideal- and nonideal solutions. I was intrigued when first reading this newly derived formalism. Being educated to calculate "deviations from Raoult" (just numbers, nothing more), suddenly nonideality acquired a very clear microscopic significance. Beautiful! I highly recommend this book to anybody interested in the subject, in particular to those of you that teach it.
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